Chemistry · Class 12 · Chapter 4
The d- and f-Block Elements
13 lessons112 min7 simulations10 practice questions
The d-block fills the wide middle of the periodic table (groups 3-12) and the f-block sits in two rows below it. The chapter explains why these metals are hard, high-melting and similar across a row, why their ionisation enthalpies and electrode potentials run irregularly, and how partly filled d orbitals give them many oxidation states, paramagnetism, colour, complexes and catalytic power. It then studies two workhorse oxidants, K₂Cr₂O₇ and KMnO₄, and closes with the lanthanoids (and the lanthanoid contraction) and the actinoids.
Also called: transition elements · lanthanides and actinides · d-block elements
Lessons
13 lessons · 112 min
01Position and electronic configurationNCERT §4.1; §4.29 min1 sim02Physical properties and atomic sizeNCERT §4.3.1; §4.3.210 min1 sim03Ionisation enthalpiesNCERT §4.3.36 min04Oxidation statesNCERT §4.3.46 min05Electrode potentialsNCERT §4.3.5; §4.3.69 min1 sim06Higher oxidation states and reactivityNCERT §4.3.7; §4.3.86 min07Magnetic propertiesNCERT §4.3.910 min1 sim08Coloured ions and complexesNCERT §4.3.10; §4.3.116 min09Catalysts, interstitial compounds and alloysNCERT §4.3.12; §4.3.13; §4.3.146 min10Potassium dichromate and permanganateNCERT §4.4; §4.4.117 min3 sims11The lanthanoidsNCERT §4.56 min12The actinoids and applicationsNCERT §4.6; §4.76 min13Chapter reviewMust-know facts, traps and formulas15 min
Simulations
7 in this chapter
Which electrons leave first when a 3d atom forms an ion?In: Position and electronic configurationWhy is hafnium no bigger than zirconium?In: Physical properties and atomic sizeWhy is copper the odd one out?In: Electrode potentialsCounting unpaired electrons with a magnetIn: Magnetic propertiesWhere exactly does the pink stay?In: Potassium dichromate and permanganateDoes chromium change when the colour does?In: Potassium dichromate and permanganateHow many electrons does permanganate take?In: Potassium dichromate and permanganate