Lesson 11 of 11 · 15 min
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Must-know facts
20 facts
- 01Work function φ₀: least energy for an electron to escape a metal surface; 1 eV = 1.602 × 10⁻¹⁹ J.
- 02Three ways out: thermionic (heat), field (about 10⁸ V m⁻¹, spark plug), photoelectric (light of suitable frequency).
- 03e/m of the electron = 1.76 × 10¹¹ C/kg; elementary charge 1.602 × 10⁻¹⁹ C (Millikan, 1913).
- 04Hertz found photoelectric emission in 1887; Hallwachs and Lenard studied it in 1886–1902.
- 05Zinc, cadmium and magnesium need ultraviolet; alkali metals (Li, Na, K, Cs, Rb) respond to visible light.
- 06Photocurrent and saturation current are proportional to intensity.
- 07Stopping potential V₀ is independent of intensity and rises linearly with frequency; Kmax = eV₀.
- 08Changing frequency at fixed intensity changes V₀ but leaves the saturation current the same.
- 09Below the threshold frequency ν₀ there is no emission, however intense the light.
- 10Emission is instantaneous: delay of about 10⁻⁹ s or less.
- 11Einstein (1905): Kmax = hν − φ₀; ν₀ = φ₀/h.
- 12V₀ = (h/e)ν − φ₀/e: slope h/e, the same for every metal; intercept on the ν axis is ν₀.
- 13Millikan (1906–1916) measured the slope for sodium and confirmed the equation; h = 6.626 × 10⁻³⁴ J s.
- 14Photon: E = hν = hc/λ, p = hν/c = h/λ, speed c, no charge.
- 15More intensity means more photons per second, not more energy per photon.
- 16Example 11.1: 2.0 mW at 6.0 × 10¹⁴ Hz → 3.98 × 10⁻¹⁹ J per photon, 5.0 × 10¹⁵ photons per second.
- 17Example 11.2: caesium, 2.14 eV → ν₀ = 5.16 × 10¹⁴ Hz; V₀ = 0.60 V → λ = 454 nm.
- 18de Broglie (1924): λ = h/p = h/mv.
- 19Electron at 5.4 × 10⁶ m/s: λ = 0.135 nm, comparable with X-rays.
- 20Ball of 0.150 kg at 30.0 m/s: λ = 1.47 × 10⁻³⁴ m, far beyond measurement.
Common traps
Where marks are lost
Formulas
8 to know
Stopping potential
Kmax = eV₀
V₀ is the smallest retarding potential that stops the photocurrent.
Einstein's photoelectric equation
Kmax = hν − φ₀
Holds for ν ≥ ν₀.
Threshold frequency
ν₀ = φ₀/h
Threshold wavelength λ₀ = hc/φ₀.
Stopping potential against frequency
V₀ = (h/e)ν − φ₀/e
Straight line of slope h/e; eV₀ = h(ν − ν₀).
Photon energy
E = hν = hc/λ
h = 6.63 × 10⁻³⁴ J s in NCERT's worked examples.
Photon momentum
p = hν/c = h/λ
Same for every photon of a given frequency.
Photons per second
N = P/E
P is the beam's power, E the energy of one photon.
de Broglie relation
λ = h/p = h/mv
Matter wave of a particle of mass m and speed v.
Key terms
16 terms
- Work function
- The least energy an electron needs to escape from a metal surface, written φ₀.
- Electron volt
- Energy an electron gains across 1 V: 1.602 × 10⁻¹⁹ J.
- Thermionic emission
- Electrons escaping from a metal that has been heated strongly.
- Field emission
- Electrons pulled out of a metal by a very strong electric field.
- Photoelectric emission
- Electrons ejected from a surface by light of suitable frequency.
- Photoelectron
- An electron released from a surface by light.
- Emitter and collector
- The photosensitive plate C that releases electrons, and the plate A that gathers them.
- Saturation current
- The largest photocurrent, reached when every emitted electron gets to the collector.
- Stopping potential
- The smallest retarding potential on the collector that brings the photocurrent to zero.
- Threshold frequency
- The lowest frequency that can eject electrons from a given metal; ν₀ = φ₀/h.
- Quantum
- A single packet of radiation energy, hν.
- Photon
- The particle of light: energy hν, momentum h/λ, speed c, no charge.
- Planck's constant
- h = 6.626 × 10⁻³⁴ J s; links a photon's energy to its frequency.
- Dual nature
- Radiation and matter each show wave behaviour in some experiments and particle behaviour in others.
- Matter wave
- The wave associated with a moving material particle.
- de Broglie wavelength
- λ = h/p, the wavelength of a particle's matter wave.